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ChemistryNEET 2024Titrimetric analysis and salt analysis

Principles Related to Practical Chemistry

During the preparation of Mohr's salt solution (ferrous ammonium sulphate), which of the following acids is added to prevent hydrolysis of the ion?

  1. A.concentrated sulphuric acid
  2. B.dilute nitric acid
  3. C.dilute sulphuric acid
  4. D.dilute hydrochloric acid

Solution

Dilute sulphuric acid suppresses hydrolysis of (which would otherwise give a turbid basic salt) without oxidising it; nitric acid would oxidise to , and HCl introduces chloride.

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