Chapter 36 of 2363 min read
First law, work and internal energy
Why this is asked: Internal energy is a state function — for an ideal gas it depends on temperature alone — while heat and work are path-dependent, so two different processes between the same states can have very different Q and W despite identical ΔU.
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- •Two gases A and B are filled at the same pressure in separate cylinders with movable pistons of radius and , respectively. On supplying an equal amount of heat to both the systems reversibly under constant pressure, the pistons of gas A and B are displaced by 16 cm and 9 cm, respectively. If the change in their internal energy is the same, then the ratio is equal to:
- •A thermodynamic system is taken through the cycle shown in the – diagram. The work done by the gas along the path is:

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