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ChemistryNEET 2024Isomerism in coordination compounds

Coordination Compounds

Match List I with List II.

List I (Complex)List II (Type of isomerism)
A. I. Solvate isomerism
B. II. Linkage isomerism
C. III. Ionisation isomerism
D. IV. Coordination isomerism

Choose the correct answer from the options given below:

  1. A.A-I, B-III, C-IV, D-II
  2. B.A-I, B-IV, C-III, D-II
  3. C.A-II, B-IV, C-III, D-I
  4. D.A-II, B-III, C-IV, D-I✓

Solution

can bind through N or O — linkage isomerism (A-II). Exchanging and between coordination sphere and counter-ion — ionisation isomerism (B-III). Two complex ions can swap ligands — coordination isomerism (C-IV). Water inside versus outside the sphere — solvate/hydrate isomerism (D-I).

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